The electron-donor properties of Sm2O3 activated at 300, 500, and 800°C are reported from studies on the adsorption of electron acceptors of various electron affinities (electron affinity values in eV are given in parentheses): 7,7,8,8-tetracyanoquino-dimethane (2.84), 2,3,5,6-tetrachloro-1,4-benzoquinone (2.40), p-dinitrobenzene (1.77), and m-dinitrobenzene (1.26) in acetonitrile and 1,4-dioxane. The extent of electron transfer during the adsorption was determined from magnetic measurements. The acid-base properties of Sm2O3 at different activation temperatures are reported using a set of Hammett indicators. Electron donor-acceptor interactions at interfaces are important in elucidating the adhesion forces.
Carboxy Terminated Liquid Natural Rubber (CTNR) was
prepared by photochemical reaction using maleic anhydride and masticated
natural rubber (NR). The use of CTNR as an adhesive in bonding rubber to
rubber and rubber to metal was studied. The peel strengths and lap shear
strengths of the adherends which were bonded using CTNR were determined.
The effect of using a tri isocyanate with CTNR in rubber to metal bonding was
also studied. It is found that CTNR can effectively be used in bonding rubber to
rubber and rubber to mild steel.