| dc.contributor.author |
Mohammed Yusuff, K K |
|
| dc.contributor.author |
Manju, Sebastian |
|
| dc.contributor.author |
Arun, Vasudevan |
|
| dc.contributor.author |
Robinson, P P |
|
| dc.contributor.author |
Leeju, Pally |
|
| dc.contributor.author |
Digna, Varghese |
|
| dc.contributor.author |
Varsha, Gopalakrishnan |
|
| dc.date.accessioned |
2010-04-24T04:48:17Z |
|
| dc.date.available |
2010-04-24T04:48:17Z |
|
| dc.date.issued |
2009-10-15 |
|
| dc.identifier.citation |
Applied Chemistry,Cochin University of Science and Technology |
en_US |
| dc.identifier.issn |
0095-8972 print/ISSN 1029-0389 online 2009 Taylor & Francis |
|
| dc.identifier.other |
DOI: 10.1080/00958970903342117 |
|
| dc.identifier.uri |
http://dyuthi.cusat.ac.in/jspui/handle/dyuthi/1638 |
|
| dc.description.abstract |
The mononuclear cobalt(II) complex [CoL2] H2O (where HL is quinoxaline-2-carboxalidine-
2-amino-5-methylphenol) has been prepared and characterized by elemental analysis, conductivity
measurement, IR, UV-Vis spectroscopy, TG-DTA, and X-ray structure determination.
The crystallographic study shows that cobalt(II) is distorted octahedral with each tridentate
NNO Schiff base in a cis arrangement. The crystal exhibits a 2-D polymeric structure parallel to
[010] plane, formed by O-H...N and O-H... O intermolecular hydrogen bonds and pye
stacking interactions, as a racemic mixture of optical enantiomers. The ligand is a Schiff base
derived from quinoxaline-2-carboxaldehyde |
en_US |
| dc.language.iso |
en |
en_US |
| dc.publisher |
Taylor & Francis, Journal of Coordination Chemistry |
en_US |
| dc.subject |
Quinoxaline-2-carboxaldehyde |
en_US |
| dc.subject |
2-Amino-5 -methylphenol |
en_US |
| dc.subject |
Crystal structure |
en_US |
| dc.subject |
Schiff base |
en_US |
| dc.subject |
Cobalt(II) |
en_US |
| dc.title |
Synthesis, characterization, and structure of a new cobalt(II) Schiff-base complex with quinoxaline- 2-carboxalidine-2-amino-5-methylphenol |
en_US |
| dc.type |
Working Paper |
en_US |