Prathapachandra Kurup, M R; Nisha, K; Sithambaresan, M(November 21, 2011)
[+]
[-]
Abstract:
The title compound, C21H19N3O2S, exists in the thione form.
The configuration about the C N bond is E. The
hydrazinecarbothioamide unit adopts an almost planar
arrangement, with maximum deviations of 0.016 (3) and
0.016 (2) A ° for the two thiourea N atoms. An intramolecular
O—H N hydrogen bond occurs. Weak intermolecular N—
H S, C—H O and C—H interactions are observed in
the crystal structure
Mohammed Yusuff, K K; Leeju, P; Arun,V; Manju, Sebastian; Varsha, Gopalakrishnan; Digna, Varghese(Crystallography Journals,Acta Crystallographica Section E ,Structure Reports, July 15, 2009)
[+]
[-]
Abstract:
In the title molecule, C16H11N5, the mean planes of the
quinoxaline and indazole fragments form a dihedral angle of
10.62 (5). In the crystal, weak intermolecular N—H..........N
hydrogen bonds link the molecules into zigzag chains
extending in the [001] direction. The crystal packing also
exhibits pye interactions [centroid–centroid distances of
3.7080 (2) and 3.8220 (5) A ˚ ], which form stacks of the
molecules parallel to the a axis
Mohammed Yusuff, K K; Digna, Varghese; Arun, Vasudevan; Manju, Sebastian; Leeju, P; Varsha, Gopalakrishnan(Crystallography Journals,Acta Crystallographica Section E ,Structure Reports, January 23, 2009)
[+]
[-]
Abstract:
In the molecule of the title compound, C20H16N6, the central
C—C bond lies on a crystallographic inversion centre. The
quinoxalidine ring is nearly planar, with a maximum deviation
of 0.021 (2) A ˚ from the mean plane. The crystal structure is
stabilized by intermolecular C—H....N interactions, leading to
the formation of a layer-like structure, which extends along the
a axis
Mohammed Yusuff, K K; Varsha, Gopalakrishnan; Arun, Vasudevan; Manju, Sebastian; Leeju, P; Digna, Varghese(Crystallography Journals,Acta Crystallographica Section E ,Structure Reports, March 24, 2009)
[+]
[-]
Abstract:
The asymmetric unit of the title compound, C11H8N4, contains
two independent molecules. In the crystal structure, intermolecular
N—H.....N hydrogen bonds link molecules into
ribbons extended in the [100] direction