A new microwave dielectric resonator Ba(Tb1/2Nb1/2)03 has been prepared and characterized in the microwave frequency region. 1 wt% CeO2 is used as additive to reduce the sintering temperature. The sintered samples were characterized by XRD, SEM and Raman spectroscopic methods. Microwave DR properties such as er, Q factor and temperature-coefficient of resonant frequency (Ti) have been measured using a HP 8510 B Network Analyzer. Cylindrical DRs of Ba(Tb1/2Nbi/2)03 showed high Er (~ 37), high Q (~3,200) and low Tf (~10 ppm /°C) at 4 GHz and hence are useful for practical applications
A new group of compounds with composition (Ba5-xSrx) Nb4015, having high
permittivity and low loss have been prepared and characterized in the microwave
frequency region . X-ray diffraction studies showed that monophase compound
existed for all values of x from 0 to 5. Microwave dielectric properties such as
and c f showed smooth variation with x , while the unloaded quality factor (Qu)
showed remarkable improvement with x
The microwave dielectric properties of (I -x)CaTiO3-xSm(Mg1/2Tit,2)O3(0.1 <-x< 1.0) have been investigated. The
system forms a solid solution throughout the entire compositional range. The dielectric constant decreases from 86 to 25 as x
varies from 0.1 to 1.0. The Qxf varies non-linearly and increases for composition with x> 0.6. The nonmonotonic variation
with composition x is more pronounced in Tt than in er. The microwave dielectric properties indicate the possibility of a phase
transformation for x between 0.4 and 0.5
Abdul Khalam,L; Sreemoolanadhan,H; Ratheesh, R; Mohanan, P; Sebastian,M T(ELSEVIER, 2003)
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Abstract:
Microwave dielectric resonators (DRs) based on Ba(B1,2Nbi/2)03 [B' = La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Y, Yb, and In] complex
perovskites have been prepared by conventional solid state ceramic route. The dielectric properties (relative permittivity, Er; quality factor, Q;
and resonant frequency, rr) of the ceramics have been measured in the frequency range 4-6 GHz using resonance methods. The resonators
have relatively high dielectric constant in the range 36-45, high quality factor and small temperature variation of resonant frequency. The
dielectric properties are found to depend on the tolerance factor (t), ionic radius (r), and lattice parameter (ap)
Dielectric ceramics based on solid solution phases of [RE1_x= REr]TiNb06, where REI_s = Nd, Pr, Sm and RE' = Dy, Gd and Y, were prepared by the conventional solid-state ceramic route for values of x. The ceramic samples are characterized by X-ray diffraction and microwave methods. Ceramics based on RE (Pr, Nd and Sm) belonging to aeschynite group shows positive value of Tf and those based on RE (Gd, Dy and Y) belonging to euxenite group show negative value of r f. The solid solution phases between the aeschynite and the euxenite group shows intermediate dielectric constant and r f values. The results indicate the possibility of tailoring the dielectric properties by varying the composition of the solid solution phases. The range of solid solubility of euxenite in aeschenite and aeschenite
in euxenite are different for different rare earth ions
Microwave dielectric ceramics based on GdTiNb,-,.Ta,O6 and Sml _.,Y,TiTa06 have been prepared by conventional solid state
method . The GdTiTaO6 and SmTiTaO6 have aeschenite structure with positive rr and GdTiNbO6 and YTiTaO6 have euxenite
structure with negative rr. The rr of the ceramics has been tuned by preparing solid solution phases between the aeschynites and
euxenites for a possible zero rr material . It is observed that GdTiNbt_YTa.,O6 undergoes a phase transition from aeschynite to
euxenite when x=0.75 and in Sml-,YxTiTa06 for x= 0.73. The microwave dielectric properties change abruptly near the transition
region . The rr value approaches zero near the phase transition region while the samples have poor sinterability and poor quality
factor . The unloaded quality factor, dielectric constant and the sign of rr of the solid solution phases are found to depend on the
average ionic radius of the rare earth ion in RE ,-5RE',TiTaO6. The boundary of the euxenite-aeschynite phase transition occurs at
an average ( RE) ionic radius of 0.915 A in Sm,_, Y,.TiTaO6 solid solution phases