We have performed thermal diffusion measurements
of nanofluid containing gold and rhodamine 6G dye
in various ratios. At certain concentrations, gold is nearly
four times more efficient than water in dissipating small
temperature fluctuations in a medium, and therefore it will
find applications as heat transfer fluids. We have employed
dual-beam mode-matched thermal lens technique for the
present investigation. It is a sensitive technique in measuring
photothermal parameters because of the use of a lowpower,
stabilized laser source as the probe. We also present
the results of fluorescence measurements of the dye in the
nanogold environment.
Sony, George; Ajai, Kumar; Singh, R K; Nampoori, V P N(Springer, 2010)
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Abstract:
A study has been carried out to understand the
influence of ambient gases on the dynamics of laser-blow-off
plumes of multi-layered LiF–C thin film. Plume images
at various time intervals ranging from 100 to 3000 ns have
been recorded using an intensified CCD camera. Enhancement
in the plume intensity and change in size and shape
occurs on introducing ambient gases and these changes are
highly dependent on the nature and composition of the ambient
gas used. Velocity of the plume was found to be
higher in helium ambient whereas intensity enhancement is
greater in argon environment. The plume shapes have maximum
size at 10−2 and 10−1 Torr of Ar and He pressures,
respectively. As the background pressure increases further
(>10−2 Torr: depending on the nature of gas), the plume
gets compressed/focused in the lateral direction. Internal
structure formation and turbulences are observed at higher
pressures (>10−1 Torr) in both ambient gases.
Usha, Nair; Bindu M, Krishna; Namboothiri, V N N; Nampoori, V P N(Springer, 2010)
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Abstract:
Machine tool chatter is an unfavorable phenomenon during metal cutting, which results in heavy vibration of cutting tool. With increase in depth of cut, the cutting regime changes from chatter-free cutting to one with chatter. In this paper, we propose the use of permutation entropy (PE), a conceptually simple and computationally fast measurement to detect the onset of chatter from the time series using sound signal recorded with a unidirectional microphone. PE can efficiently distinguish the regular and complex nature of any signal and extract information about the dynamics of the process by indicating sudden change in its value. Under situations where the data sets are huge and there is no time for preprocessing and fine-tuning, PE can effectively detect dynamical changes of the system. This makes PE an ideal choice for online detection of chatter, which is not possible with other conventional nonlinear methods. In the present study, the variation of PE under two cutting conditions is analyzed. Abrupt variation in the value of PE with increase in depth of cut indicates the onset of chatter vibrations. The results are verified using frequency spectra of the signals and the nonlinear measure, normalized coarse-grained information rate (NCIR).
Santhi Ani, Joseph; Gaurav, Sharma; Misha, Hari; Mathew, S; Radhakrishnan, P; Nampoori, V P N(Optical Society of America, 2010)
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Abstract:
We demonstrate the possibility of realizing, all-optical switching in gold nanosol. Two overlapping laser beams are used for this purpose, due to which a low-power beam passing collinear to a high-power beam will undergo cross phase modulation and thereby distort the spatial profile. This is taken to advantage for performing logic operations. We have also measured the threshold pump power to obtain a NOT gate and the minimum response time of the device. Contrary to the general notion that the response time of thermal effects used in this application is of the order of milliseconds, we prove that short pump pulses can result in fast switching. Different combinations of beam splitters and combiners will lead to the formation of other logic functions too.
Nampoori, V P N; Radhakrishnan, P; Litty, Irimpan(Science of Advanced Materials , American Scientific Publishers, 2010)
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Abstract:
The spectral and nonlinear optical properties of ZnO based nanocomposites prepared by colloidal
chemical synthesis are investigated. Very strong UV emissions are observed from ZnO–Ag, ZnO–
Cu and ZnO–SiO2 nanocomposites. The strongest visible emission of a typical ZnO–Cu nanocomposite
is over ten times stronger than that of pure Cu due to transition from deep donor level to the
copper induced level. The optical band gap of ZnO–CdS and ZnO–TiO2 nanocomposites is tunable
and emission peaks changes almost in proportion to changes in band gap. Nonlinear optical
response of these nanocomposites is studied using nanosecond laser pulses from a tunable laser in
the wavelength range of 450–650 nm at resonance and off-resonance wavelengths. The nonlinear
response is wavelength dependent and switching from RSA to SA has been observed at resonant
wavelengths. Such a change-over is related to the interplay of plasmon/exciton band bleach and
optical limiting mechanisms. The observed nonlinear absorption is explained through two photon
absorption followed by weak free carrier absoption, interband absorption and nonlinear scattering
mechanisms. The nonlinearity of the silica colloid is low and its nonlinear response can be improved
by making composites with ZnO and ZnO–TiO2. The increase of the third-order nonlinearity in the
composites can be attributed to the enhancement of exciton oscillator strength. This study is important
in identifying the spectral range and the composition over which the nonlinear material acts
as an RSA based optical limiter. These nanocomposites can be used as optical limiters and are
potential materials for the light emission and for the development of nonlinear optical devices with
a relatively small limiting threshold.
V P N Nampoori; Mohammed Yusuff, K K; Arun,V; Mathew, S; Robinson, P P; Jose,M(Elsevier, Journal of Dyes and Pigments, March 20, 2010)
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Abstract:
The Schiff base, 3-hydroxyquinoxaline-2-carboxalidine-4-aminoantipyrine, was synthesized by the
condensation of 3-hydroxyquinoxaline-2-carboxaldehyde with 4-aminoantipyrine. HPLC, FT-IR and NMR
spectral data revealed that the compound exists predominantly in the amide tautomeric form and
exhibits both absorption and fluorescence solvatochromism, large stokes shift, two electron quasireversible
redox behaviour and good thermal stability, with a glass transition temperature of 104oC. The
third-order non-linear optical character was studied using open aperture Z-scan methodology employing
7 ns pulses at 532 nm. The third-order non-linear absorption coefficient, b, was 1.48 x 10-6 cm W-1 and
the imaginary part of the third-order non-linear optical susceptibility, Im c(3), was 3.36 x10-10 esu. The
optical limiting threshold for the compound was found to be 340 MW cm-2.
Nampoori, V P N; Senoy, Thomas; Jinesh, Mathew; Radhakrishnan, P; George, A K; Al-Harthi,R V; Ramanujan, R V; Anantharaman, M R(Sensors and Actuators: A Physical, May 11, 2010)
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Abstract:
Metallic glass alloy Metglas 2826 MB based amorphous magnetic thin films were
fabricated by the thermal evaporation technique. Transmission electron micrographs and
electron diffraction pattern showed the amorphous nature of the films. Composition of
the films was analyzed employing x-ray photoelectron spectroscopy and energy
dispersive x-ray spectroscopy techniques. The film was integrated to a long period fibre
grating. It was observed that the resonance wavelength of the fibre grating decreased with
an increase in the magnetic field. Change in the resonance wavelength was minimal at
higher magnetic fields. Field dependent magnetostriction values revealed the potential
application of these films in magnetostrictive sensor devices
Geetha K, Varier; Harilal, S S; Bindhu, C V; Riju, C Issac; Nampoori, V P N; Vallabhan, C P G(December 3, 2011)
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Abstract:
Irradiation of a Polymethyl methacrylate target using a pulsed Nd-YAG laser causes plasma formation in the vicinity of the target. The refractive index gradient due to the presence of the plasma is probed using phase-shift detection technique. The phase-shift technique is a simple but sensitive technique for the determination of laser ablation threshold of solids. The number density of laser generated plasma above the ablation threshold from Polymethyl methacrylate is calculated as a function of laser fluence. The number density varies from 2×1016 cm-3 to 2×1017 cm-3 in the fluence interval 2.8-13 J · cm-2.