Abstract: | The nanosecond optical limiting characteristics of sandwich-type neodymium diphthalocyanine in a co-polymer matrix of polymethyl methacrylate (PMMA) and methyl-2-cyanoacrylate have been studied for the first time. The measurements were performed using 9 ns laser pulses generated from a frequency-doubled Nd:YAG laser at 532 nm wavelength. The optical limiting performance of neodymium diphthalocyanine in co-polymer host was studied at different linear transmission. Laser damage threshold was also measured for the doped and undoped co-polymer samples. The optical limiting response is attributed to reverse saturable absorption which is due to excited-state absorption. |
URI: | http://dyuthi.cusat.ac.in/purl/2605 |
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Dyuthi-P0165.pdf | (454.6Kb) |
Abstract: | Recent developments on nanostructured conducting polymer-inorganic composites systems have receieved considerable research interest owing to their unique synergestic properties compared with their individual bulk counter parts which make them promising candidates for a broad spectrum of high technological applications such as in energy conversion, electronic devices, storage, sensors, actuators, memory devices, and biomedical devices. Nanostructured conducting polymers possess unique features such as high specific surface area, high charge carrier concentration, high electrical conductivity, high mechanical flexibility, light weight, solution processability and printability over a large area which make them favourable for their high tech applications. Among the conducting polymers, polyanilline, poly(3,4-ethylene dioxy thiophene), poly(N-vinylcarbzole) are receiving much importance due to their low cost, environmental stability and unique doping mechanism. Conversely, semiconducting inorganic metal oxide such as zinc oxide and titania nanomaterials have emerged as an area of intense research interest motivated by their potential applications in electronics, non-linear optics, and magnetic devices due to their low band gap, small crystalline size and unique opto-electronic properties. In this perspective, studies on the development and applications of semiconducting polymer-inorganic metal oxide nanocomposite are interesting since it is expected to exhibit synergistic properties arising from the molecular level mixing of conducting polymer and inorganic counter parts. |
URI: | http://dyuthi.cusat.ac.in/purl/5146 |
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Dyuthi-T2180.pdf | (34.32Mb) |
Abstract: | Various synthesis routes have been developed in recent years for the preparation of nanoparticles. One of those methods is polymer induced crystallization. The first objective of the present work was to prepare nano ZnO powder by polymer induced crystallization in chitosan solution and to characterize the material using different techniques like TEM, SEM, XRD, FTLR, UV spectroscopy, TGA, DSC etc.The second object of the study is to prepare composites using nano ZnO. It has been undertaken to explore the potential of nano ZnO as reinforcement in engineering as well as commodity thermoplastics to widen their application spectra. We selected three engineering thermoplastics like [poly ethylene terephthalate, polyamide 6, and polycarbonate] and three commodity plastics like [polypropylene, high density polyethylene, and polystyrene] for the study. To date one of the few disadvantages associated with nanoparticle incorporation has concerned toughness and impact performance. Modification of polymers could reduce impact performance. The present study also focused on whether nano ZnO can act as a modifier for thennoplastics, without sacrificing their impact strength. |
Description: | Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology |
URI: | http://dyuthi.cusat.ac.in/purl/2555 |
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Dyuthi-T0699.pdf | (17.28Mb) |
Abstract: | HINDI |
Description: | Department of Hindi, Cochin University of Scienc and Technology |
URI: | http://dyuthi.cusat.ac.in/purl/4846 |
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Dyuthi-T1943.pdf | (4.687Mb) |
Abstract: | Sensitisation of natural rubber latex by addition of a small quantity of an anionic surfactant prior to the addition of a coacervant results in quick coagulation. The natural rubber prepared by the novel coagulation method shows improved raw rubber characteristics, better cure characteristics in gum and carbon black filled compounds and improved mechanical properties as compared to the conventionally coagulated natural rubber. Compounds based on dried masterbatches prepared by the incorporation of fluffy carbon black in different forms of soap sensitised natural rubber latices such as fresh latex, preserved field latex, centrifuged latex and a blend of preserved field latex and skim latex show improved cure characteristics and vucanizate properties as compared to an equivalent conventional dry rubber-fluffy carbon black based compound. The latex masterbatch based vulcanizates show higher level of crosslinking and better dispersion of filler. Vulcanizates based on fresh natural rubber latex- dual filler masterbatches containing a blend of carbon black and silica prepared by the modified coagulation process shows very good mechanical and dynamic properties that could be correlated to a low rolling resistance. The carbon black/silica/nanoclay tri-filler - fresh natural rubber latex masterbatch based vulcanizates show improved mechanical properties as the proportion of nanoclay increased up to 5 phr. The fresh natural rubber latex based carbon black-silica masterbatch/ polybutadiene blend vulcanizates show superior mechanical and dynamic properties as compared to the equivalent compound vulcanizates prepared from the dry natural rubber-filler (conventional dry mix)/polybutadiene blends |
Description: | Department of Polymer Science and Rubber Technology Cochin University of Science and Technology |
URI: | http://dyuthi.cusat.ac.in/purl/4745 |
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Dyuthi-T1843.pdf | (4.453Mb) |
Abstract: | The present work "Nature and Ecological Significance of Nutrient Regeneration in different Prawn Culture Fields" was undertaken to understand the seasonal variation of nutrients, nutrient cycling and primary productivity of the prawn culture systems. The main emphasis was to find the qualitative and quantitative estimates of distribution of total phosphorus, inorganic phosphorus, organic phosphorus, total nitrogen and nitrogen fractions in the water. The effect of nutrient cycling on primary productivity and concentration of metals also form one part of the study. The entire thesis comprise of only one major chapter with subchapters such as, Introduction (I), Review of Literature (2), Material and Methods (3), Results (14), Discussion (5), Executive Summary (6) and Biblio~ graphy (7) |
Description: | Centre of Advanced Studies in Mariculture,Cochin University Of Science And Technology |
URI: | http://dyuthi.cusat.ac.in/purl/3603 |
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Dyuthi-T1562.pdf | (11.74Mb) |
Description: | Department Of Hindi, Cochin University of Science And Technology |
URI: | http://dyuthi.cusat.ac.in/purl/3744 |
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Dyuthi-T1706.pdf | (775.8Kb) |
URI: | http://dyuthi.cusat.ac.in/purl/5620 |
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Dyuthi T-2661.pdf | (760.9Kb) |
URI: | http://dyuthi.cusat.ac.in/purl/1106 |
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Radhakrishnan P 1986.pdf | (1.269Mb) |
Abstract: | Laser-induced damage is the principal limiting constraint in the design and operation of high-power laser systems used in fusion and other high-energy laser applications. Therefore, an understanding of the mechanisms which cause the radiation damage to the components employed in building a laser and a knowledge of the damage threshold of these materials are of great importance in designing a laser system and to operate it without appreciable degradation in performance. This thesis, even though covers three distinct problems for investigations using a dye Q-switched multimode Nd:glass laser operating at 1062 nm and emitting 25 ns (FWHM) pulses, lays its main thrust on damage threshold studies on thin films. Using the same glass laser two-photon excited fluorescence in rhodamine 6G and generation and characterisation of a carbon plasma have also been carried out. |
Description: | Department of Physics, Cochin University Of Science And Technology |
URI: | http://dyuthi.cusat.ac.in/purl/3761 |
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Dyuthi-T1723.pdf | (11.63Mb) |
Abstract: | Laser-induced damage is the principal limiting constraint in the design and operation of high-power laser systems used in fusion and other high-energy laser applications. Therefore, an understanding of the mechanisms which cause the radiation damage to the components employed in building a laser and a knowledge of the damage threshold of these materials are of great importance in designing a laser system and to operate it without appreciable degradation in performance. This thesis, even though covers three distinct problems for investigations using a dye Q-switched multimode Nd:glass laser operating at 1062 nm and emitting 25 ns (FWHM) pulses, lays its main thrust on damage threshold studies on thin films. Using the same glass laser two-photon excited fluorescence in rhodamine 6G and generation and characterisation of a carbon plasma have also been carried out. The thesis is presented in seven chapters. |
Description: | Department of Physics, Cochin university of Science and Technology |
URI: | http://dyuthi.cusat.ac.in/purl/3316 |
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Dyuthi-T1315.pdf | (11.63Mb) |
Abstract: | Nearly half of lanthanum sites in lanthanum manganites were substituted with monovalent ion-sodium and the compound possessed distorted orthorhombic structure. Ferromagnetic ordering at 300K and the magnetic isotherms at different temperature ranges were analyzed for estimating magnetic entropy variation. Magnetic entropy change of 1.5 J kg 1 K 1 was observed near 300 K. An appreciable magnetocaloric effect was also observed for a wide range of temperatures near 300K for small magnetic field variation. Heat capacity was measured for temperatures lower than 300K and the adiabatic temperature change increases with increase in temperature with a maximum of 0.62K at 280 K |
Description: | APPLIED PHYSICS LETTERS 104, 092407 (2014) |
URI: | http://dyuthi.cusat.ac.in/purl/4427 |
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Near fifty perc ... mperature applications.pdf | (1.450Mb) |
Abstract: | In the title molecule, C16H11N5, the mean planes of the quinoxaline and indazole fragments form a dihedral angle of 10.62 (5). In the crystal, weak intermolecular N—H..........N hydrogen bonds link the molecules into zigzag chains extending in the [001] direction. The crystal packing also exhibits pye interactions [centroid–centroid distances of 3.7080 (2) and 3.8220 (5) A ˚ ], which form stacks of the molecules parallel to the a axis |
URI: | http://dyuthi.cusat.ac.in/purl/1649 |
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leeju.pdf | (199.0Kb) |
Abstract: | Modeling of chaotic systems, based on the output time series, is quite promising since the output often represents the characteristic behaviour of the total system. It has been an interesting topic for researchers over the past few years. So far, some methods are developed for the identification of chaotic systems. Because of the intense complexity of chaotic systems, the performance of existing algorithms is not always satisfactory. Application of chaotic system theory to socially relevant problems like environmental studies is the need of the hour Neural networks have the required self-learning capability to tune the network parameters (i.e. weights) for identifying highly non-linear and chaotic systems. In the present work, effectiveness of modeling a chaotic system using dynamic neural networks has been demonstrated. From the rich literature available for non-linear modeling with neural networks, the Recurrent Neural Network (RNN) structure is selected. The Extended Kalman Filter (EKF) algorithm is used to train the RNN. Further, the Expectation Maximization algorithm is used to effectively arrive at the initial states and the state covariance. Particle filter algorithm with its two important variants namely Sampling Importance Resampling (SIR) and Rao Blackwellised algorithms are also used for training the given RNN. Four standard chaotic systems, Lorenz, Rossler, Chua and Chen, are modelled with the three algorithms. The best algorithm is found to be EKF-EM based on the least mean square error criterion. Validation of RNN model with EKFEM algorithm is done in time domain by Estimation of embedding dimension, Phase plots, Lyapunov Exponents, Kaplan -Yorke dimension and Bifurcation diagrams. Analysis of the chaotic systems is also performed in the transform domain using Fourier, Wavelet and Mapped Real Transforms. viii Natural chaotic systems are analyzed based on the selected model structure and training algorithm, taken for analysis. Sunspot, Venice Lagoon and North Atlantic oscillations are the three of the natural chaotic systems modelled with the selected RNN model structure and EKF-EM algorithm. |
URI: | http://dyuthi.cusat.ac.in/purl/5162 |
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Dyuthi-T2196.pdf | (6.188Mb) |
Description: | International School of Photonics, Cochin University of Science and Technology |
URI: | http://dyuthi.cusat.ac.in/purl/2556 |
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Dyuthi-T0700.pdf | (11.28Mb) |
Abstract: | Pyridoxal 5'-phosphate (PLP) is the major coenzymatic form of pyridoxine. There are over one hundred known pyridoxal 5'-phosphate-dependent reactions, most of which are involved in the metabolism of various amino acids . Pyridoxamine 5'-phosphate can function in aminotransf erase reactions by the cyclic regeneration of the two active phosphate forms. Pyridoxal 5'-phosphate-dependent reactions studied in the nervous system are involved in the catabolism of various amino acids. The putative neurotransmitters , dopamine, norepinephrine , serotonin , histamine , aminobutyric acid and taurine , as well as the sphingoiipids and poly amines are synthesized by PLP-dependent enzymes. Of these enzymes, three ( glutamic acid decarboxylase , 5-hydroxytryptophan decarboxylase and crnithine decarboxylase) seem to have crucial roles (Fig. '). The clinical effects of pyridoxine deficiency can be explained on the basis of the known decreases in the activities of these enzymes |
URI: | http://dyuthi.cusat.ac.in/purl/600 |
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K Dakshinamurti and others (1985) PDF.PDF | (14.43Mb) |
Abstract: | Veuruenducrim lri v j p .rim, deficienc:v. NEUROSCI BIOBEHAV REV 12(3/4) 189-193. 1988.- Dihydroxyphenylalanine decarboxvlase and 5-hydroxytryptophan decarboxvlase respectively have high and low affinities for pyridoxal phosphate. In the pyridoxinedeficient animal. hypothalamic serotonin content is significantly reduced without any change in catecholamine levels. Hypothalamic neurotransmitters affect the hvpothalamo-pituitary-end organ axes. Specifically, the decrease in hypothalamic serotonin in the pyridoxine-deficient rat results in tertiary hypothyroidism. In addition. pineal function is affected in deficient animals due to decreased synthesis of melatonin. |
URI: | http://dyuthi.cusat.ac.in/purl/598 |
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K Dakshinamurti and others (1988) PDF.PDF | (4.117Mb) |
URI: | http://dyuthi.cusat.ac.in/purl/577 |
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Simon Chiu and others(1981)11dec7.PDF | (2.020Mb) |
Abstract: | This thesis Entitled Neuronal degeneration in streptozotocin induced diabetic rats: effect of aegle marmelose and pyridoxine in pancreatic B cell proliferation and neuronal survival. Diabetes mellitus, a chronic metabolic disorder results in neurological dysfunctions and structural changes in the CNS. Antioxidant therapy is a challenging but necessary dimension in the management of diabetes and neurodegenerative changes associated with it. Our results showed regional variation and imbalance in the expression pattern of dopaminergic receptor subtypes in diabetes and its role in imbalanced insulin signaling and glucose regulation. Disrupted dopaminergic signaling and increased hyperglycemic stress in diabetes contributed to the neuronal loss. Neuronal loss in diabetic rats mediated through the expression of pattern of GLUT-3, CREB, IGF-1, Akt-1, NF,B, second messengers- cAMP, cGMP, IP3 and activation of apoptotic factors factors- TNF-a,caspase-8. Disrupted dopaminergic receptor expressions and its signaling in pancreas contributed defective insulin secretion in diabetes. Activation of apoptotic factors- TNF- a,caspase-8 and defective functioning of neuronal survival factors, disrupted second messenger signaling modulated neuronal viability in diabetes. Hyperglycemic stress activated the expression of TNF-a,caspase-8, BAX and differential expression of anti oxidant enzymes- SOD and GPx in liver lead to apoptosis. Treatment of diabetic rats with insulin, Aegle marmelose and pyridoxine significantly reversed the altered dopaminergic neurotransmission, GLUT3, GLUT2, IGF-1 and second messenger signaling. Antihyperglycemic and antioxidant activity of Aegle marmelose and pyridoxine enhanced pancreatic B cell proliferation, increased insulin synthesis and secretion in diabetic rats. Thus our results conclude the neuroprotective and regenerating ability of Aegle marmelose and pyridoxine which in turn has a novel therapeutic role in the management of diabetes. |
Description: | Center for neuroscience, Department of Biotechnology, Cochin University of Science and Technology |
URI: | http://dyuthi.cusat.ac.in/purl/3040 |
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Dyuthi-T1014.pdf | (26.10Mb) |
Abstract: | Neuroscience is the study of'tbe ne rvous system , including the i - ; . in, spinal cord and peripheral nerves . Neurons are the basic cells of the brain and nervous system which exerts its functional role through various neurotransmitters and receptor systems . The activity of a nen ren depends on the balance between the number of excitatory and inhibito r y processes affecting it, both processes occurring individually and sin ,tlte-' ,ieously. The functional bal,ince of different neurotransmitters such as Acct >>lcholine (Ach), Dopamine (DA), Serotonin (5-1-17), Nor epinepbri,te (N.1 j, Epinephrine (LPI), Glutamate and Gamma amino butyric acid (GA BA) regulates the growth , division and other vital functions ofa normal cell / organisin (Sudha, 1 998). The micro-environ ; nertt of the cell is controlled / the macro-environment that surrounds the individual. Any change in the cell environment causes imbalance in cell homeostasis and f,ntction. Pollution is a significant cause of imbalance caused iii the inacYcenvironment. Interaction with polluted environments can have an adverse impact on the health of humans. The alarming rise in enviromilmieil cont.iniin :rtion has been linked to rises in levels of pesticides, ndltstr al effluents, domestic Waste, car exhausts and other anthropogenic activities. Persistent exposures to contaminant cause a negative imp,-, on brain health and development . Pollution also causes a change in the neurotransmitters and their receptor function leading to earl.;' recurrence of neurodcge,terative disorders such as flypoxia , Alzbeimers's and Huntington 's disease early in life. |
URI: | http://dyuthi.cusat.ac.in/purl/649 |
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Dr. P Natarajan and others(.PDF | (7.142Mb) |
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